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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/50563

Title: [N(CH2CH2NH3)3][U3O2F13]·2H2O:  A Novel Organically Templated Mixed-Valent Uranium Oxyfluoride with a Hybrid Network Structure
Authors: Chih-Min Wang
Chia-Hsien Liao
Hsiu-Mei Lin
Kwang-Hwa Lii
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2004
Issue Date: 2018-10-15T06:31:05Z
Publisher: Inorganic Chemistry
Abstract: Abstract: The synthesis and characterization of a novel mixed-valent uranium oxyfluoride is described; the inorganic network consists of 2-D [U2F10]2- sheets constructed from corner- and edge-sharing UIVF9 tricapped trigonal prisms and 1-D [UO2F3]- chains constructed from edge-sharing UVIO2F5 pentagonal bipyramids with the organic cations and water molecules between the sheets. This is the first example with a hybrid network structure in the system of uranium fluoride or oxyfluoride. The variable-temperature magnetic susceptibility confirms the oxidation state of the uranium ions. Crystal data follow:  C6H25N4O4F13U3, monoclinic, space group P21 (No. 4); a = 8.6876(4) Å, b = 7.3158(4) Å, c = 16.3376(8) Å, β = 93.7285(9)°, V = 1036.2(2) Å3, and Z = 2.
Relation: 43(26) pp.8239-8241
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/50563
Appears in Collections:[生命科學暨生物科技學系] 期刊論文

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