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Title: Solvothermal Synthesis of Two Polymorphs of an Indium Germanate Incorporating an Organic Amine Ligand: β- and γ-In2Ge6O15(NH2CH2CH2NH2)2
Authors: Chih-Min Wang
Ciao-Wei Yang
Chia-Hui Lin
Kwang-Hwa Lii
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2010-12
Issue Date: 2018-10-15T03:29:47Z
Publisher: Inorg. Chem
Abstract: Abstract: Two new polymorphs, β- and γ-In2Ge6O15(NH2CH2CH2NH2)2, have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge6O15] that are connected by In2O6N4 octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.
Relation: 49(22) pp.10229-10231
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/50552
Appears in Collections:[生命科學暨生物科技學系] 期刊論文

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