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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/50444

Title: A series of organic-inorganic hybrid zinc phosphites containing extra-large channels
Authors: Wang CM
Pan MF
Lin YJ
Chung MY
Wen YS
Chang Y
Lin HM
Hsu T
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2018-03
Issue Date: 2018-10-08T06:41:54Z
Publisher: Inorganic Chemistry
Abstract: Abstract: A series of organic-inorganic hybrid zinc phosphites with extra-large channels were synthesized and characterized by single-crystal X-ray diffraction. This is an unusual example of introducing 1,4-benzenedicarboxylate and/or biphenyl-4,4'-dicarboxylate ligands into the organically templated metal phosphite system to build extra-large-channel zeolite-related materials via hydro(solvo)thermal reactions. Those frameworks are composed of carboxylate linkers and inorganic tubes of zinc phosphites, translating their channel windows from a square shape (NTOU-1) to rhombus forms (NTOU-2 and NTOU-3) via the replacement of organic amines or ligands under synthesis conditions otherwise identical with those used to prepare NTOU-1. The synthesis, structural diversity, photoluminescence, and adsorption properties for dye molecules and lanthanide ions are also reported.
Relation: 57(5) pp.2390-2393
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/50444
Appears in Collections:[生命科學暨生物科技學系] 期刊論文

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