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Title: Bis(mu-di-2-pyridylaminato 1-oxide)bis[(trifluoroacetato)copper(II)] Acetonitrile Disolvate
Authors: Zeng, X.-R
Fang, X.-N
Peng, S.-M
Lin, H.-M
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2003-11
Issue Date: 2018-10-08T03:24:11Z
Publisher: Acta Crystallographica Section C Crystal Structure Communications
Abstract: Abstract: The crystal structure of the title compound, [Cu-2(C2F3O2)(2)-(C10H8N3O)(2)].2CH(3)CN, contains discrete [Cu-2(CF3COO)(2)-(O-dpa)(2)] molecules (O-dpaH is di-2-pyridylamine 1-oxide) which have imposed crystallographic twofold symmetry and an acetonitrile molecule of solvation. The O-dpa(-) ligand is both bidentate and bridging, linking two Cu atoms with a separation of 3.4270 (11) Angstrom. Each Cu atom is surrounded by four coordinated atoms that are almost coplanar, with dimensions Cu-N = 1.940 (2) and 1.984 (3) Angstrom, and Cu-O = 1.912 (2) and 1.945 (2) Angstrom.
Relation: 59 pp.497-498
Appears in Collections:[Department of Bioscience and Biotechnology ] Periodical Articles

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