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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/48246

Title: HER Catalytic Activity of Electrodeposited Ni-P Nanowires under the Influence of Magnetic Field
Authors: Hung-Bin Lee
Jiun-Chen Tsau
Chun-Ying Lee
Contributors: 國立臺灣海洋大學:光電與材料科技學系
Date: 2013-10
Issue Date: 2018-08-20T05:42:10Z
Publisher: Journal of Nanomaterials
Abstract: Abstract: Nickel alloy electrodes both in plane and nanowire morphologies were fabricated by electrodeposition in sulfamate bath. With the increasing concentration of phosphorous acid in the electrolyte, the P content in the deposition increased accordingly. In the meantime, the grain refined and even became amorphous in microstructure as the P content was raised. For the nanowire electrode, vibrating sample magnetometer (VSM) measurement showed that its coercivity was anisotropic and decreased with P-content. In addition, the easy axis for magnetization of the electrode was parallel to the axial direction of nanowire. The electrocatalytic activity measurement of the electrode in 0.5 M H2SO4 electrolyte showed that the nanowire electrode had higher activity than the plane one, and the alloying of P in Ni electrode raised its hydrogen evolution reaction (HER) performance. The enhanced performance of nanowire electrode was attributed to the smaller and more uniform hydrogen bubbles generated in HER reaction. Finally, the applied magnetic field (3.2 T) improved significantly the HER activity of Ni but not Ni-P electrode. By using nanowire morphology and applying magnetic field, the current density at −0.75 V HER stability test of the Ni electrode increased fourfold more than its plane counterpart.
Relation: 2013(11)
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/48246
Appears in Collections:[光電科學研究所] 期刊論文

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