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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/48143

Title: Formation and Corrosion Behavior of Mechanically-Alloyed Cu–Zr–Ti Bulk Metallic Glasses
Authors: Pee-Yew Lee
Yeh-Ming Cheng
Jyun-Yu Chen
Chia-Jung Hu
Contributors: 國立臺灣海洋大學:光電與材料科技學系
Keywords: mechanical alloying
bulk metallic glass
corrosion
supercooled liquid region
vacuum hot pressing
Date: 2017-04
Issue Date: 2018-08-14T03:03:38Z
Publisher: Metals
Abstract: Abstract: Cu60Zr30Ti10 metallic glass powder was prepared by mechanically alloying a mixture of pure Cu, Zr, and Ti powders after 5 h of milling. Cu60Zr30Ti10 bulk metallic glass (BMG) was synthesized by vacuum hot pressing the as-milled Cu60Zr30Ti10 metallic glass powder at 746 K in the pressure range of 0.72–1.20 GPa, and the structure was analyzed through X-ray diffraction and transmission electron microscopy. The pressure could enhance the thermal stability, and prolong the existence, of the amorphous phase inside the Cu60Zr30Ti10 powder. Furthermore, the corrosion behavior of the Cu-based BMG in four corrosive media was studied using a potentiodynamic method. The Cu60Zr30Ti10 BMG exhibited a low corrosion rate and current density in 1 N solutions of H2SO4, NaOH, and HNO3. X-ray photoelectron spectroscopy results revealed that the formation of Zr- and Ti-rich passive oxide layers provides a high corrosion resistance against 1 N H2SO4 and HNO3 solutions, and the breakdown of the protective film by Cl− attack was responsible for pitting corrosion in a 3 wt % NaCl solution. The formation of oxide films and the nucleation and growth of pitting were analyzed through microstructural investigations.
Relation: 7(4)
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/48143
Appears in Collections:[光電科學研究所] 期刊論文

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