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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/48127

Title: Reducing gas –sensing performance of Ce-doped SnO2 thin films through a cosputtering method
Authors: Yuan-Chang Liang
C.M. Lee
Y.J. Lo
Contributors: 國立臺灣海洋大學:光電與材料科技學系
Date: 2017-01
Issue Date: 2018-08-13T08:15:02Z
Publisher: RSC Advances
Abstract: Abstract: SnO2 thin films doped with various concentrations of Ce were grown by cosputtering Sn and Ce metallic targets in an Ar/O2 mixed atmosphere. The cerium concentrations in the SnO2 films were varied from 1.2 to 4.5 at% by varying the Ce sputtering power during thin-film growth. Surface morphology analysis revealed that the surface roughness of the Ce-doped SnO2 thin films increased with an increase in cerium concentration. X-ray diffraction and transmission electron microscopy analysis results indicated that the Ce-doped SnO2 thin films were highly crystalline. Furthermore, Ce ions in the SnO2 thin films had mixed valence states; moreover, the oxygen vacancy density increased with an increase in Ce concentration. An increased Ce concentration in the SnO2 thin films engendered the roughening of the Ce-doped SnO2 film surface and increased the concentration of Ce4+ ions and oxygen vacancy number near the film surface. These factors are advantageous for enabling the adsorption of a relatively large number of oxygen ions on the film surface; therefore, increased ethanol vapor sensing responses of Ce-doped SnO2 thin films with an increase in Ce concentration were observed in this study.
Relation: 7(8) pp.4724-4734
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/48127
Appears in Collections:[光電科學研究所] 期刊論文

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