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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/45580

Title: UF3(H2O)(C2O4)0.5: A Fluorooxalate of Tetravalent Uranium with a Three-Dimensional Framework Structure
Authors: Chih-Min Wang;Chia-Hsien Liao;Pei-Lin Chen;Kwang-Hwa Lii
Contributors: 國立臺灣海洋大學:生命科學系
Date: 2006
Issue Date: 2018-03-27T06:21:31Z
Publisher: Inorganic Chemistry
Abstract: Abstract: A new uranium(IV) fluorooxalate, UF3(H2O)(C2O4)0.5, has been synthesized by a hydrothermal method and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of two-dimensional layers of corner- and edge-sharing tricapped trigonal prisms with the composition UF4/2F2/2O3 linked by bisbidentate oxalate ligands to form a three-dimensional framework. Magnetic susceptibilities were measured to confirm the tetravalent state of uranium. Crystal data:  monoclinic, space group C2/c, a = 17.246(3) Å, b = 6.088(1) Å, c = 8.589(2) Å, β = 95.43(3)°, and Z = 8.
Relation: 45(4)
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/45580
Appears in Collections:[生命科學系] 期刊論文

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