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Title: Solvothermal Synthesis and Structural Characterization of Two Polymorphs of In2Ge6O15(NH2CH2CH2NH2)2.
Authors: Chih-Min Wang;Ciao-Wei Yang;Chia-Hui Lin;Kwang-Hwa Lii
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2010
Issue Date: 2016-10-25T08:36:58Z
Publisher: Inorg. Chem
Abstract: Abstract: Two new polymorphs, β- and γ-In(2)Ge(6)O(15)(NH(2)CH(2)CH(2)NH(2))(2), have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge(6)O(15)] that are connected by In(2)O(6)N(4) octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.
Relation: 49(22)
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/38656
Appears in Collections:[生命科學系] 期刊論文

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