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Title: Synthesis, characterization and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe2O6(OH)2(CH3CH(NH2)CH2NH2)·2H2O
Authors: WANG Chih-Min;CHIU Cheng-Wei;LIN Hsiu-Mei;LII Kwang-Hwa
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2003
Issue Date: 2016-10-25T08:09:47Z
Publisher: Journal of solid state chemistry
Abstract: Abstract: A new indium borogermanate incorporating an organic amine ligand, InBGe2O6(OH)2(CH3CH(NH2) CH2NH2) · 2H2O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In2O6N4 octahedral dimers, Ge2O6(OH) double tetrahedra, and BO3(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm.
Relation: 208
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/38653
Appears in Collections:[生命科學系] 期刊論文

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