English  |  正體中文  |  简体中文  |  Items with full text/Total items : 28611/40649
Visitors : 644689      Online Users : 52
RC Version 4.0 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
Scope Adv. Search

Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/38651

Title: New Nanostructured Zinc Phosphite Templated by Cetyltrimethylammonium Cations: Synthesis, Crystal Structure, Adsorption, and Photoluminescence Properties
Authors: Chih-Min Wang;Tsung-Yuan Chang;Cheng-Wei Chiu;Hsiu-Mei Lin;Kwang-Hwa Lii
Contributors: 國立臺灣海洋大學:生命科學暨生物科技學系
Date: 2014
Issue Date: 2016-10-25T07:59:20Z
Publisher: Journal of American Chemical Society
Abstract: Abstract: Nanostructured zinc phosphite templated by cetyltrimethylammonium (CTA+) cations was synthesized using a hydro(solvo)thermal method. This is the first example of a crystalline metal phosphite containing long carbon tails of the CTA+ ions as templates in its structure, as is structurally characterized by single-crystal X-ray diffraction. The 2D inorganic structures with 4.82 topologies are constructed from the interconnection of tetrahedral ZnO3Br and HPO3 units, which are sandwiched between CTA+ ion surfactants in a packing behavior of a largely lamellar liquid-crystalline structure to extend the interlayer d spacing to 28.05 Å. Adsorption experiment shows selective adsorption properties of 1-naphthol and a adsorption capacity of 0.17 mmol/mmol (CTA)ZnBr(HPO3). This compound has potential as an adsorbent for the removal of 1-naphthol pollutant from wastewater. In addition, the naphthol-adsorbed sample shows interesting luminescent properties that are different from that of an as-synthesized sample. The crystal structure, thermal stability, IR spectrum, adsorption, and photoluminescence properties have been studied.
Relation: 53(7)
URI: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/38651
Appears in Collections:[生命科學系] 期刊論文

Files in This Item:

File Description SizeFormat

All items in NTOUR are protected by copyright, with all rights reserved.


著作權政策宣告: 本網站之內容為國立臺灣海洋大學所收錄之機構典藏,無償提供學術研究與公眾教育等公益性使用,請合理使用本網站之內容,以尊重著作權人之權益。
網站維護: 海大圖資處 圖書系統組
DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - Feedback