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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/27539

Title: Photoluminescence Enhancement of Y3Al5O12:Ce Nanoparticles Using HMDS
Authors: Yung-Tang Nien;Kun-Ming Chen;In-Gann Chen;Tai-Yuan Lin
Contributors: NTOU:Institute of Optoelectronic Sciences
國立臺灣海洋大學:光電科學研究所
Date: 2008-11
Issue Date: 2011-10-21T02:32:06Z
Publisher: Journal of the American Ceramic Society
Abstract: Abstract: Coprecipitated Y3Al5O12:Ce (YAG:Ce) nanoparticles, treated with hexamethyldisilazane (HMDS) at 150°C for 1 h in an autoclave and then fired at 980°C, showed an enhanced photoluminescence (PL) intensity compared with pure YAG:Ce without any HMDS treatment. X-ray diffraction analysis revealed a shift of the (420) peak to a higher angle with more HMDS addition, indicating the decreasing lattice parameter caused by the substitution of Al3+ sites with Si4+ ions in the YAG host. Transmission electron micrographs showed a smaller size and more dispersal of YAG:Ce nanoparticles with more HMDS addition, which was caused by OH-scavenging methyl siloxyl groups. Diffuse reflectivity showed identical absorption behavior for pure and HMDS-treated YAG:Ce, suggesting the same amount of Ce3+ activators in the YAG host. Therefore, the enhancement of the PL intensity of HMDS-treated YAG:Ce was supposed to be a result of an increasing diffusion and a homogeneous distribution of Ce3+ activators in YAG, due to the smaller Si4+ ions and the formation of Al3+ vacancies, based on the longer decay time measured.
Relation: 91(11), pp.3599-3602
URI: http://ntour.ntou.edu.tw/handle/987654321/27539
Appears in Collections:[光電科學研究所] 期刊論文

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