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Please use this identifier to cite or link to this item: http://ntour.ntou.edu.tw:8080/ir/handle/987654321/27083

Title: Polymerization of a Confined π-System: Chemical Synthesis of Tetrahedral Amorphous Carbon Nanoballs from Graphitic Carbon Nanocapsules
Authors: C.-C. Chu;G.-L. Hwang;J.-W. Chiou;W.-F. Pong;C.-L. Lin;C.-Y. Tsai;H.-M. Lin;Y.-C. Chang;C.-S. Chang;A. H. Hsu;W.-L. Huang;J. Guo;P.-H. Chen;T.-Y. Luh
Contributors: NTOU:Institute of Bioscience and Biotechnology
Keywords: Amorphous materials;Carbon nanostructures;Nanostructures;Pyrolysis
Date: 2005-11
Issue Date: 2011-10-21T02:22:35Z
Publisher: Advanced Materials
Abstract: Abstract:Aziridination of graphitic carbon nanocapsules (CNCs) followed by pyrolysis at 700 degrees C at ambient pressure yields tetrahedral amorphous carbon nanoballs (CNBs, see Figure). Because of the pyramidal character of some of the double bonds in the derivatized CNCs, a radical chain mechanism is proposed to rationalize the transformation of C sp(2) hybridization in the CNCs to C sp(3) hybridization in the CNBs.
Relation: 17(22), pp.2707–2710
URI: http://ntour.ntou.edu.tw/handle/987654321/27083
Appears in Collections:[生命科學暨生物科技學系] 期刊論文

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